Le Chatelier's principle

Le Châtelier's principle is a principle used in chemistry and physics to describe how a system at equilibrium reacts to external changes. Equilibrium in a reversible reaction is when the forward reaction happens at the same rate as the reverse reaction. So the reactions don't stop happening, but the opposite reactions cancel each other out. In Le Châtelier's principle, reactions go to equilibrium after the environment is changed by shifting in the opposite direction of the change.

Overview

It is used to show how the point of equilibrium of a system will move to oppose a change in the conditions of the system, following Newton's third law. This is most commonly seen in reversible reactions in chemistry, where a chemical reaction has reached a point where the formation of products happens at the same rate the products decay back into reactants. This principle can then be used to increase the amount of desired products made by moving equilibrium towards that side in chemical industries.

Concentration

If the concentration of reactants in a reaction increases, the point of equilibrium moves towards the products as this gets rid of the some of excess reactants and cancels the change. Similarly, if the concentration of products increases, the equilibrium moves towards the reactants.

Pressure

If the pressure of a system increases, the point of equilibrium will shift to the side with less moles of gas. This is where the coefficients of the gases added up are less than that of the other side. That side will occupy less volume and therefore will reduce the pressure.

Temperature

If the temperature of a system is increased, the point of equilibrium moves towards whichever side doesn't have heat. In exothermic reactions, heat is a product so the reaction will shift left. In endothermic reactions, heat is a reactant so the reaction will shift right.This will take in the excess energy as part of the products and so cancels the change of increased temperature.

Electromagnetism

This principle is also shown by Lenz's law, which states that a changing magnetic flux will produce an opposing magnetic flux (and therefore a magnetic and electric field) in any nearby metals. This will then produce a second current in the nearby metal in the opposite direction to the original current.

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