Arsenic trisulfide
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| Names | |
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| Preferred IUPAC name
Arsenic trisulfide | |
| Other names
Arsenic(III) sulfide Orpiment | |
| Identifiers | |
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3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.013.744 |
| EC Number |
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PubChem CID |
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| RTECS number |
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| UNII | |
CompTox Dashboard (EPA) |
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SMILES
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| Properties | |
| As2S3 | |
| Molar mass | 246.02 g·mol−1 |
| Appearance | Orange crystals |
| Density | 3.43 g cm−3 |
| Melting point | 310 °C (590 °F; 583 K) |
| Boiling point | 707 °C (1,305 °F; 980 K) |
| -70.0·10−6 cm3/mol | |
| Structure[1] | |
Space group |
P21/n (No. 11) |
Lattice constant |
a = 1147.5(5) pm
, b = 957.7(4) pm , c = 425.6(2) pmα = 90°, β = 90.68(8)°, γ = 90°
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| pyramidal (As) | |
| Hazards[2][3] | |
| GHS labelling: | |
Pictograms |
Template:GHS06Template:GHS09 |
Signal word |
Danger |
Hazard statements |
H300, H331, H400, H411 |
| NFPA 704 (fire diamond) | |
| NIOSH (US health exposure limits): | |
PEL (Permissible) |
[1910.1018] TWA 0.010 mg/m3 |
REL (Recommended) |
Ca C 0.002 mg/m3 [15-minute] |
IDLH (Immediate danger) |
Ca [5 mg/m3 (as As)] |
| Related compounds | |
Other anions |
Arsenic trioxide Arsenic triselenide |
Other cations |
Phosphorus trisulfide Antimony trisulfide Bismuth sulfide |
Related compounds |
Tetraarsenic tetrasulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is  ?) | |
| Infobox references | |
Arsenic trisulfide, also known as orpiment or arsenic(III) sulfide, is a chemical compound. Its chemical formula is As2S3. It has arsenic and sulfide ions in it. The arsenic is in its +3 oxidation state.
Properties
Arsenic trisulfide is a yellow solid. It is a semiconductor. It has a glass (amorphous) form and a crystalline form. It burns in air to make sulfur dioxide and arsenic trioxide, which makes a highly toxic smoke. Arsenic trisulfide can oxidize on the surface to make a highly toxic layer of arsenic trioxide as well. Arsenic trisulfide is not toxic unless it oxidizes. It does not react with acids.
Occurrence
Preparation
Arsenic trisulfide is made when an arsenic compound like arsenic trichloride reacts with hydrogen sulfide. It is also made when arsenic and sulfur are heated together.
Uses
It was looked at for treating cancer. It was used by the Egyptians as a pigment and cosmetic. It is used in glass.
References
- ↑ Mullen, D. J. E.; Nowacki, W (1972), "Refinement of the crystal structures of realgar, AsS and orpiment, As2S3" (PDF), Z. Kristallogr., 136 (1–2): 48–65, doi:10.1524/zkri.1972.136.1-2.48, archived from the original (PDF) on 2010-06-28, retrieved 2011-10-18.
- ↑ Template:CLP Regulation
- ↑ "Arsenic, inorganic compounds (as As)", 29 C.F.R. § 1910.1018, 58 FR 35310, June 30, 1993, as amended. Template:PGCH-ref.